One-pot synthesis of nanomaterials via RAFT polymerization induced self-assembly and morphology transition.
نویسندگان
چکیده
A simple and facile strategy has been developed for synthesis of nanomaterials via polymerization in high concentration; multiple morphologies can be created and tuned just by variation of the feed ratio and reaction conditions.
منابع مشابه
Study on RAFT Polymerization and Nano-structured Hybrid System of POSS Macromers
This work is generally aimed to synthesize POSS based BCPs via RAFT polymerization, to study their self-assembly behaviors, to research on the effect of POSS self-assembly structure on the bulk properties and to prepare nanostructured hybrid epoxy via self-assembly of POSS based copolymer. In Chapter1, We studied the RAFT polymerization of POSS macromers and capable to synthesize well defined P...
متن کاملPolymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization
In this Perspective, we discuss the recent development of polymerization-induced self-assembly mediated by reversible addition-fragmentation chain transfer (RAFT) aqueous dispersion polymerization. This approach has quickly become a powerful and versatile technique for the synthesis of a wide range of bespoke organic diblock copolymer nano-objects of controllable size, morphology, and surface f...
متن کاملSynthesis of Silica/Polystyrene Nanocomposite Particles by Miniemulsion Polymerization
Miniemulsion polymerization is one of heterogeneous polymerization method that can be effectively used to synthesis of various novel organic-inorganic nanocomposite particles. This method can provide opportunity of good incorporation between the polymer and inorganic phases in the formed submicrometer-sized particles. In this article, we report preparation polystyrene/silica nanocomposite p...
متن کاملRAFT-Mediated Polymerization-Induced Self-Assembly of Poly(Acrylic Acid)-b-Poly(Hexafluorobutyl Acrylate): Effect of the pH on the Synthesis of Self-Stabilized Particles
This paper describes a very simple strategy towards self-stabilized poly(acrylic acid)-block-poly(hexafluorobutyl acrylate) (PAA-b-PHFBA) block copolymer particles via reversible addition-fragmentation chain transfer (RAFT)-mediated polymerization-induced self-assembly. Hexafluorobutyl acrylate (HFBA) monomer conversion and number-average molar mass of PAA-b-PHFBA increased gradually with the i...
متن کاملSynthesis of hollow polymeric nanoparticles for protein delivery via inverse miniemulsion periphery RAFT polymerization.
Hollow polymeric nanoparticles with a hydrophilic liquid core have been synthesized in a one-pot approach via a novel inverse miniemulsion periphery RAFT polymerization process. Successful encapsulation and release of a model protein is reported as a potential application.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 39 شماره
صفحات -
تاریخ انتشار 2009